The Lithium Aluminum Hydride Reduction of p-Substituted Stilbene Oxides
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چکیده
منابع مشابه
Reduction of Halomethanes with Lithium Aluminum Hydride
A study has been made of t he reactions of lithium aluminum hydride with methyl bromide, methylene chloride, meth ylene bromide, methylene iodide, chloroform, bromoform, and carbon t etrachloride. Except for hydrogen and unreacted h alida, essentia lly pure methane was formed in each case. The amount of hydrogen evolved increased with the n umber of halogen atoms in the molecule, reaching a max...
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Lithium aluminum hydride (LiAlH(4)) is a promising compound for hydrogen storage, with a high gravimetric and volumetric hydrogen density and a low decomposition temperature. Similar to other metastable hydrides, LiAlH(4) does not form by direct hydrogenation at reasonable hydrogen pressures; therefore, there is considerable interest in developing new routes to regenerate the material from the ...
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The dipolar cycloaddition reactivity of N-(1-naphthy1)-1,4- benzoquinoneimine N-oxide and N-phenyl-1,4- naphthoquinoneimine Noxide are investigated, The latter gives the expected adducts with common dipolarophiles such as acrylonitryle, methyl methacrylate, dimethylacetylene dicarboxylate and N-phenylmaleimide. The reactivity of the former nitrone is found to be minimal. It undergoes, how...
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Anion photoelectron spectroscopy and density functional theory were employed to study aluminum hydride clusters, AlnHm (4 e n e 8, 0 e m e 10). Photoelectron spectra revealed that Al4H4, Al4H6, and a family of species with general formula AlnHn+2 (5 e n e 8) have small adiabatic electron affinities and large HOMO-LUMO gaps (ranging from 0.5 to 1.9 eV) relative to those of their stoichiometric n...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 1954
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja01635a048